Rational Design of 2D Supramolecular Networks Switchable by External Electric Fields
2 Year Impact Factor 2023: 15.8
| Main Authors: | , , , , , , , , |
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| Format: | info:eu-repo/semantics/publishedVersion |
| Language: | eng |
| Published: |
2024
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| Subjects: | |
| Online Access: | http://hdl.handle.net/11086/552728 https://pubs.acs.org/doi/full/10.1021/acsnano.3c09775 https://pubmed.ncbi.nlm.nih.gov/38259041/ |
| _version_ | 1806012162892627968 |
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| author | Cometto, Fernando P. Arisnabarreta, Nicolás Vanta, Radovan Jacquelín, Daniela K. Vyas, Vijay Lotsch, Bettina V. Paredes Olivera, Patricia A. Patrito, E. Martín Lingenfelder, Magalí |
| author2 | https://orcid.org/0000-0002-0825-2312 |
| author_facet | https://orcid.org/0000-0002-0825-2312 Cometto, Fernando P. Arisnabarreta, Nicolás Vanta, Radovan Jacquelín, Daniela K. Vyas, Vijay Lotsch, Bettina V. Paredes Olivera, Patricia A. Patrito, E. Martín Lingenfelder, Magalí |
| author_sort | Cometto, Fernando P. |
| collection | Repositorio Digital Universitario |
| description | 2 Year Impact Factor 2023: 15.8 |
| format | info:eu-repo/semantics/publishedVersion |
| id | rdu-unc.552728 |
| institution | Universidad Nacional de Cordoba |
| language | eng |
| publishDate | 2024 |
| record_format | dspace |
| spelling | rdu-unc.5527282024-07-13T06:24:06Z Rational Design of 2D Supramolecular Networks Switchable by External Electric Fields Cometto, Fernando P. Arisnabarreta, Nicolás Vanta, Radovan Jacquelín, Daniela K. Vyas, Vijay Lotsch, Bettina V. Paredes Olivera, Patricia A. Patrito, E. Martín Lingenfelder, Magalí https://orcid.org/0000-0002-0825-2312 https://orcid.org/0000-0002-9546-1250 https://orcid.org/0000-0002-1770-603X https://orcid.org/0000-0002-9309-0249 https://orcid.org/0000-0002-3094-303X https://orcid.org/0000-0002-0218-8946 https://orcid.org/0000-0002-5817-966X https://orcid.org/0000-0003-1362-8879 Chemical structure Interfaces Molecular structure Molecules Scanning tunneling microscopy 2 Year Impact Factor 2023: 15.8 info:eu-repo/semantics/publishedVersion Fil: Cometto Fernando P. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Fil: Cometto Fernando P. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina. Fil: Cometto Fernando P. Max Planck-EPFL. Laboratory for Molecular Nanoscience and IPHYS, Lausanne; Switzerland. Fil: Arisnabarreta, Nicolás. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Fil: Arisnabarreta, Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina. Fil: Arisnabarreta, Nicolás. Max Planck-EPFL. Laboratory for Molecular Nanoscience and IPHYS, Lausanne; Switzerland. Fil: Vanta, Radovan. Max Planck-EPFL. Laboratory for Molecular Nanoscience and IPHYS, Lausanne; Switzerland. Fil: Jacquelín, Daniela K. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Fil: Jacquelín, Daniela K. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina. Fil: Vyas, Vijay. Max Planck. Institute for Solid State Research, Stuttgart; Germany Fil: Lotsch, Bettina V. Max Planck Institute for Solid State Research, Stuttgart; Germany. Fil: Lotsch, Bettina V. University of Munich. Department of Chemistry, Munich; Germany. Fil: Paredes Olivera, Patricia A. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Teórica y Computacional; Argentina. Fil: Patrito, E. Martín. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Fil: Patrito, E. Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina. Fil: Lingenfelder, Magalí. Max Planck-EPFL Laboratory for Molecular Nanoscience and IPHYS, Lausanne; Switzerland. The reversible formation of hydrogen bonds is a ubiquitous mechanism for controlling molecular assembly in biological systems. However, achieving predictable reversibility in artificial two-dimensional (2D) materials remains a significant challenge. Here, we use an external electric field (EEF) at the solid/liquid interface to trigger the switching of H-bond-linked 2D networks using a scanning tunneling microscope. Assisted by density functional theory and molecular dynamics simulations, we systematically vary the molecule-to-molecule interactions, i.e., the hydrogen-bonding strength, as well as the molecule-to-substrate interactions to analyze the EEF switching effect. By tuning the building block’s hydrogen-bonding ability (carboxylic acids vs aldehydes) and substrate nature and charge (graphite, graphene/Cu, graphene/SiO2), we induce or freeze the switching properties and control the final polymorphic output in the 2D network. Our results indicate that the switching ability is not inherent to any particular building block but instead relies on a synergistic combination of the relative adsorbate/adsorbate and absorbate/substrate energetic contributions under surface polarization. Furthermore, we describe the dynamics of the switching mechanism based on the rotation of carboxylic groups and proton exchange, which generate the polarizable species that are influenced by the EEF. This work provides insights into the design and control of reversible molecular assembly in 2D materials, with potential applications in a wide range of fields, including sensors and electronics. info:eu-repo/semantics/publishedVersion Fil: Cometto Fernando P. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Fil: Cometto Fernando P. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina. Fil: Cometto Fernando P. Max Planck-EPFL. Laboratory for Molecular Nanoscience and IPHYS, Lausanne; Switzerland. Fil: Arisnabarreta, Nicolás. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Fil: Arisnabarreta, Nicolás. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina. Fil: Arisnabarreta, Nicolás. Max Planck-EPFL. Laboratory for Molecular Nanoscience and IPHYS, Lausanne; Switzerland. Fil: Vanta, Radovan. Max Planck-EPFL. Laboratory for Molecular Nanoscience and IPHYS, Lausanne; Switzerland. Fil: Jacquelín, Daniela K. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Fil: Jacquelín, Daniela K. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina. Fil: Vyas, Vijay. Max Planck. Institute for Solid State Research, Stuttgart; Germany Fil: Lotsch, Bettina V. Max Planck Institute for Solid State Research, Stuttgart; Germany. Fil: Lotsch, Bettina V. University of Munich. Department of Chemistry, Munich; Germany. Fil: Paredes Olivera, Patricia A. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Química Teórica y Computacional; Argentina. Fil: Patrito, E. Martín. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina. Fil: Patrito, E. Martín. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Fisicoquímica de Córdoba; Argentina. Fil: Lingenfelder, Magalí. Max Planck-EPFL Laboratory for Molecular Nanoscience and IPHYS, Lausanne; Switzerland. 2024-07-12T16:06:03Z 2024-07-12T16:06:03Z 2024-01-23 article Cometto, F. P., Arisnabarreta, N., Vanta, R., Jacquelín, D. K., Vyas, V., Lotsch, B. V., ... & Lingenfelder, M. (2024). Rational design of 2D supramolecular networks switchable by external electric fields. ACS nano, 18(5), 4287-4296. http://hdl.handle.net/11086/552728 1936-086X https://pubs.acs.org/doi/full/10.1021/acsnano.3c09775 https://pubmed.ncbi.nlm.nih.gov/38259041/ doi.org/10.1021/acsnano.3c09775 eng Attribution 4.0 International http://creativecommons.org/licenses/by/4.0/ |
| spellingShingle | Chemical structure Interfaces Molecular structure Molecules Scanning tunneling microscopy Cometto, Fernando P. Arisnabarreta, Nicolás Vanta, Radovan Jacquelín, Daniela K. Vyas, Vijay Lotsch, Bettina V. Paredes Olivera, Patricia A. Patrito, E. Martín Lingenfelder, Magalí Rational Design of 2D Supramolecular Networks Switchable by External Electric Fields |
| title | Rational Design of 2D Supramolecular Networks Switchable by External Electric Fields |
| title_full | Rational Design of 2D Supramolecular Networks Switchable by External Electric Fields |
| title_fullStr | Rational Design of 2D Supramolecular Networks Switchable by External Electric Fields |
| title_full_unstemmed | Rational Design of 2D Supramolecular Networks Switchable by External Electric Fields |
| title_short | Rational Design of 2D Supramolecular Networks Switchable by External Electric Fields |
| title_sort | rational design of 2d supramolecular networks switchable by external electric fields |
| topic | Chemical structure Interfaces Molecular structure Molecules Scanning tunneling microscopy |
| url | http://hdl.handle.net/11086/552728 https://pubs.acs.org/doi/full/10.1021/acsnano.3c09775 https://pubmed.ncbi.nlm.nih.gov/38259041/ |
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